Experimental Investigation of the Upper Thermal Stability of Mg-rich Actinolite; Implications for Kiruna-Type Iron Deposits   总被引：2，自引：0，他引：2  

Lledo  Haroldo L.; Jenkins  David M. 《Journal of Petrology》2008,49(2):225-238

The occurrence of actinolite in magnetite deposits of possiblemagmatic origin has prompted an experimental investigation ofthe upper thermal stability of Mg-rich actinolite to determinehow the stability of actinolite changes with increasing Fe content.Experiments were carried out primarily on the compositionalre-equilibration of natural tremolite [molar Fe/(Fe + Mg) =Fe-number = 0·014] in the presence of synthetic clinopyroxene(Ca_0·80Fe_0·67Mg_0·54Si_2·00O₆), syntheticpigeonite/orthopyroxene (Ca_0·08Fe_1·19Mg_0·70Si_2·02O₆),quartz, and water to a more Fe-rich actinolite over the rangeof 600–880°C, 1 and 4 kbar, at the Ni–NiO oxygenbuffer, for durations of 1–2 weeks. The bulk compositionof the mineral mixture is close to actinolite with Fe-number= 0·5. These experiments constitute a half-reversal ofthe amphibole composition, which, when approached from a Mg-richstarting composition, provides information on the minimum Fecontent of actinolite at a given temperature. Compositionalchanges were monitored by electron microprobe analysis of amphibolerim compositions and/or overgrowths on the original tremolite.At 4 kbar and 880–800°C, tremolite shows strong re-equilibrationwith overgrowths of an Fe-rich but low-Ca (1·7 > Ca> 1·4) actinolite; Fe-rich cummingtonite (Ca <0·7)begins to nucleate at 860°C. At 800–700°C, tremoliteshows weak compositional re-equilibration but strong nucleationof Fe-rich cummingtonite. Similar results were observed at 1kbar, with tremolite showing strong re-equilibration to low-Caactinolite at 790–600°C with cummingtonite nucleationat 800°C and below. The wide variation in Ca contents ofthe re-equilibrated amphiboles was unexpected. Additional univariantreversal experiments were carried out on the thermal decompositionof a natural actinolite (Fe-number = 0·22) from PleitoMelón, Chile, indicating the breakdown of actinoliteto clinopyroxene, orthopyroxene, quartz, and water at 780°Cand 1 kbar, and 850°C and 4 kbar. Considering only amphiboleswith Ca >1·7 a.p.f.u., the thermal stability of actinoliteis observed to decrease in a linear manner over the P–Trange investigated with a dT/dFe-number slope of –372°C/Fe-numberat 1 kbar and –546°C/Fe-number at 4 kbar. The highthermal stabilities (750–900°C) of actinolites withFe-numbers in the range of 0–0·4 overlap with therange of water-saturated melting for a typical andesite or tonalite.These conditions also overlap the field of experimental Fe–P-richmelt formation, suggesting that actinolite may have an igneousorigin in Kiruna-type ore deposits. KEY WORDS: actinolite; mineral stability; Kiruna deposits, thermodynamic values; cummingonite  相似文献   

Hydrothermal gold mineralization at the Hira Buddini gold mine,India: constraints on fluid evolution and fluid sources from boron isotopic compositions of tourmaline     

M. -S. Krienitz  R. B. Trumbull  A. Hellmann  J. Kolb  F. M. Meyer  M. Wiedenbeck 《Mineralium Deposita》2008,43(4):421-434

We determined the boron isotope and chemical compositions of tourmaline from the Hira Buddini gold deposit within the Archean Hutti-Maski greenstone belt in southern India to investigate the evolution of the hydrothermal system and to constrain its fluid sources. Tourmaline is a minor but widespread constituent in the inner and distal alteration zones of metabasaltic and metadacite host rocks associated with the hydrothermal gold mineralization. The Hira Buddini tourmaline belongs to the dravite–schorl series with variations in Al, Fe/(Fe+Mg), Ca, Ti, and Cr contents that can be related to their host lithology. The total range of δ¹¹B values determined is extreme, from −13.3‰ to +9.0‰, but 95% of the values are between −4 and +9‰. The boron isotope compositions of metabasalt-hosted tourmaline show a bimodal distribution with peak δ¹¹B values at about −2‰ and +6‰. The wide range and bimodal distribution of boron isotope ratios in tourmaline require an origin from at least two isotopically distinct fluid sources, which entered the hydrothermal system separately and were subsequently mixed. The estimated δ¹¹B values of the hydrothermal fluids, based on the peak tourmaline compositions and a mineralization temperature of 550°C, are around +1 and +10‰. The isotopically lighter of the two fluids is consistent with boron released by metamorphic devolatilization reactions from the greenstone lithologies, whereas the ¹¹B-rich fluid is attributed to degassing of I-type granitic magmas that intruded the greenstone sequence, providing heat and fluids to the hydrothermal system. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Time relationships between volcanism–plutonism–alteration–mineralization in Cu-stratabound ore deposits from the Michilla mining district,northern Chile: a <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronological approach     

Verónica Oliveros  Dania Tristá-Aguilera  Gilbert Féraud  Diego Morata  Luis Aguirre  Shoji Kojima  Fernando Ferraris 《Mineralium Deposita》2008,43(1):61-78

The Michilla mining district comprises one of the most important stratabound and breccia-style copper deposits of the Coastal Cordillera of northern Chile, hosted by the Middle Jurassic volcanic rocks of the La Negra Formation. ⁴⁰Ar/³⁹Ar analyses carried out on igneous and alteration minerals from volcanic and plutonic rocks in the district allow a chronological sequence of several magmatic and alteration events of the district to be established. The first event was the extrusion of a thick lava series of the La Negra Formation, dated at 159.9 ± 1.0 Ma (2σ) from the upper part of the series. A contemporaneous intrusion is dated at 159.6 ± 1.1 Ma, and later intrusive events are dated at 145.5 ± 2.8 and 137.4 ± 1.1 Ma, respectively. Analyzed alteration minerals such as adularia, sericite, and actinolite apparently give valid ⁴⁰Ar/³⁹Ar plateau and miniplateau ages. They indicate the occurrence of several alteration events at ca. 160–163, 154–157, 143–148, and 135–137 Ma. The first alteration event, being partly contemporaneous with volcanic and plutonic rocks, was probably produced in a high thermal gradient environment. The later events may be related either to a regional low-grade hydrothermal alteration/metamorphism process or to plutonic intrusions. The Cu mineralization of the Michilla district is robustly bracketed between 163.6 ± 1.9 and 137.4 ± 1.1 Ma, corresponding to dating of actinolite coexisting with early-stage chalcocite and a postmineralization barren dyke, respectively. More precisely, the association of small intrusives (a dated stock from the Michilla district) with Cu mineralization in the region strongly suggests that the main Michilla ore deposit is related to a magmatic/hydrothermal event that occurred between 157.4 ± 3.6 and 163.5 ± 1.9 Ma, contemporaneous or shortly after the extrusion of the volcanic sequence. This age is in agreement with the Re–Os age of 159 ± 16 Ma obtained from the mineralization itself (Tristá-Aguilera et al., Miner Depos, 41:99–105,2006).  相似文献   

Deep‐water foreland basin deposits of the Cerro Toro Formation,Magallanes basin,Chile: architectural elements of a sinuous basin axial channel belt     

STEPHEN M. HUBBARD  BRIAN W. ROMANS  STEPHAN A. GRAHAM 《Sedimentology》2008,55(5):1333-1359

Coarse‐grained deep‐water strata of the Cerro Toro Formation in the Cordillera Manuel Señoret, southern Chile, represent the deposits of a major channel belt (4 to 8 km wide by >100 km long) that occupied the foredeep of the Magallanes basin during the Late Cretaceous. Channel belt deposits comprise a ca 400 m thick conglomeratic interval (informally named the ‘Lago Sofia Member’) encased in bathyal fine‐grained units. Facies of the Lago Sofia Member include sandy matrix conglomerate (that show evidence of traction‐dominated deposition and sedimentation from turbulent gravity flows), muddy matrix conglomerate (graded units interpreted as coarse‐grained slurry‐flow deposits) and massive sandstone beds (high‐density turbidity current deposits). Interbedded sandstone and mudstone intervals are present locally, interpreted as inner levée deposits. The channel belt was characterized by a low sinuousity planform architecture, as inferred from outcrop mapping and extensive palaeocurrent measurements. Laterally adjacent to the Lago Sofia Member are interbedded mudstone and sandstone facies derived from gravity flows that spilled over the channel belt margin. A levée interpretation for these fine‐grained units is based on several observations, which include: (i) palaeocurrent measurements that indicate flows diverged (50° to 100°) once they spilled over the confining channel margin; (ii) sandstone beds progressively thin, away from the channel belt margin; (iii) evidence that the eroded channel base was not very well indurated, including a stepped margin and injection of coarse‐grained channel material into surrounding fine‐grained units; and (iv) the presence of sedimentary features common to levées, including slumped units inferring depositional slopes dipping away from the channel margin, lenticular sandstone beds thinning distally from the channel margin, soft sediment deformation and climbing ripples. The tectonic setting and foredeep architecture influenced deposition in the axial channel belt. A significant downstream constriction of the channel belt is reflected by a transition from more tabular units to an internal architecture dominated by lenticular beds associated with a substantially increased degree of scour. Differential propagation of the fold‐thrust belt from the west is speculated to have had a major control on basin, and subsequently channel, width. The confining influence of the basin slopes that paralleled the channel belt, as well as the likelihood that numerous conduits fed into the basin along the length of the active fold‐thrust belt to the west, suggest that proximal–distal relationships observed from large channels in passive margin settings are not necessarily applicable to axial channels in elongate basins.  相似文献   

Controls on Holocene deep‐water sedimentation in the northern Gioia Basin,Tyrrhenian Sea     

FABIANO GAMBERI  MICHAEL MARANI 《Sedimentology》2008,55(6):1889-1903

The northern Gioia Basin of the south‐east Tyrrhenian Sea is a slope basin, ～ 20 km wide and ～ 50 km long, with a bathymetry of ≤ 1300 m, bounded by the Calabro‐Sicilian landmass and the Aeolian Island Arc. Coarse sediment is supplied from the Calabrian margin, where the shelf is very narrow to non‐existent, whereas the wider shelf on the Sicilian margin prevents supply by storing river‐fed sediments. The basin is dominated by the Gioia–Mesima canyon/channel system paralleled by a tongue‐shaped depositional lobe. Multibeam bathymetric surveys, sea floor reflectivity data and airgun seismic profiles reveal the recent evolution of the submarine system. Slope canyons and basin‐floor levéed channels formed where major rivers built deltas at the shelfless Calabrian margin and strong hyperpycnal flows predominated. The channels are a few hundred metres wide and a few tens of metres deep, with a downslope change from a straight to meandering pattern where the slope gradient decreases from 3·2% to 1·7%. The Mesima Channel has its lower segment abandoned because of avulsion and crevasse‐splay formation at an upslope bend. The adjacent Gioia Channel has had its upper segment straightened and lower segment entrenched because of erosional deepening of the Stromboli Valley into which it debouches and which acts as the local base level. Overbank features include levées, coalescent splays and ‘yazoo’ channels; their nature and surface characteristics depend upon the magnitude and sediment grain‐size of spill‐over flows. On an adjoining narrow shelf sliver of the Calabrian margin, in contrast, the coalescing plumes of sediment suspension supplied by an array of smaller coastal streams were apparently spilling over the shelf edge, scouring a funnel‐shaped bypass depression with chutes and forming an elongate, non‐channellized depositional lobe at the slope base. The study demonstrates the impact of sediment source type, shelf width, basin‐floor gradient and base‐level change on the style of deep‐water sedimentation.  相似文献   

Distinguishing tectonically-and gravity-driven synsedimentary deformation structures along the Apulian platform margin (Gargano Promontory,southern Italy)     

《Marine and Petroleum Geology》2016

The assessment of deformation types within the slope of a carbonate platform can be complicated by the possible interaction of rooted (tectonically-induced) and superficial (gravity-driven) structures. An ideal case study to document and distinguish tectonically- and gravity-driven structures is provided by the Cretaceous slope-to-basin carbonates exposed in the Gargano Promontory, southern Italy. These carbonates formed adjacent to the Apulian platform margin, which was oriented approximately NE–SW to NW–SE along the southern and northern edges of the promontory, respectively. Slump-related folds are characterised by axial planes typically oriented either sub-parallel or at small angles to the strike of the inferred paleoslope. In fact, the strike of folds is roughly NE–SW in the southern portion of the study area, whereas it is NW–SE in the northern part. Correspondingly, gravity-driven normal and reverse faults strike sub-parallel and at acute angles to the adjacent Apulian paleoslope. Cretaceous tectonic faults in the slope-to-basin carbonates form two principal sets striking NW–SE and WNW-ESE. The former set is made up of normal faults and the latter one includes mainly oblique-slip normal faults. Neither normal nor oblique-slip normal faults show any relationship with the geometry of the paleoslope. The results obtained from this study may help the interpretation of subsurface data in those geological contexts in which the interplay of gravitational and tectonic processes is responsible for deformation.  相似文献   

Neogene-Quaternary contourite and related deposition on the West Shetland Slope and Faeroe-Shetland Channel revealed by high-resolution seismic studies     

Damuth  John E.  Olson  Hilary Clement 《Marine Geophysical Researches》2001,22(5-6):369-398

The Neogene and Quaternary sediments of the Faeroe-Shetland Channel and West Shetland shelf and slope rest upon a major regional unconformity, the Latest Oligocene Unconformity (LOU), and have been deposited through the interaction of downslope and parallel-to-slope depositional processes. The upper to middle continental slope is dominated by mass-transport deposits (debris flows), which progressively diminish downslope, and were largely generated and deposited during glacial cycles when ice sheets supplied large quantities of terrigeneous sediment to the upper slope and icebergs scoured sea-floor sediments on the outer shelf and uppermost slope. Large-scale sediment failures have also occurred on the upper slope and resulted in deposition of thick, regionally extensive mass-transport deposits on portions of the lower slope and channel floor. In contrast, large fields of migrating sediment waves and drift deposits dominate most of the middle to lower slope below 700 m water depth and represent deposition by strong contour currents of the various water masses moving northeastward and southwestward through the channel. These migrating sediment waves indicate strong northeastward current flow at water depths shallower than 700 m and strong southwestward current flow at water depths from 700 to >1,400 m. These flow directions are consistent with present-day water-mass flow through the Faeroe-Shetland Channel. The Faeroe-Shetland Channel floor is underlain by thin conformable sediments that appear to be predominantly glacial marine and hemipelagic with less common turbidites and debris flows. No evidence is observed in seismic or core data that indicates strong contour-current erosion or redistribution of sediments along the channel floor.  相似文献   

长江口的台风浪及其对崇明东滩的冲淤作用   总被引：1，自引：0，他引：1  

茅志昌 《海洋学研究》1993,11(4):8-16

本文分析了多年的台风和波浪资料得到如下的结果:对崇明东滩有较大影响的台风路径主要有两类:即在浙江中部至长江口登陆的台风和在长江口外侧海域转向北上的台风;佘山岛海洋站百年一遇的最大波高为5.6m;台风期间偏北、东北、东南的强风向均能引起长江口较大的增水现象。 本文还以8310号台风为例,阐明了台风前后的冲淤变化及台风浪塑造的滩地地貌形态。指出东旺沙和北八效高潮滩冲淤甚微,中低潮滩冲刷严重,奚东沙高潮滩冲刷严重,中低潮滩呈微淤状态。波浪对东滩塑造的主要地貌形态有冲刷坑和浪蚀泥坎。  相似文献   

陕西凤太地区“八卦庙式”金矿控矿因素及其找矿潜力分析   总被引：2，自引：0，他引：2  

李建华 《矿产与地质》2008,22(1):62-64

陕西风县八卦庙特大型金矿床以其超百吨级规模著称于世,借鉴其成矿规律及找矿模式在风太泥盆纪地层中开展金矿找矿工作,目前已发现次生晕金异常近百个,矿点＋余处,且多数异常尚未深入检查。笔者试图总结归纳“八卦庙式”金矿之控矿因素,并对该类型的金矿成矿远景加以分析,旨在为今后的找矿工作选区提供参考。  相似文献   

碰撞造山带斑岩型矿床的深部约束机制   总被引：19，自引：8，他引：11  

罗照华  卢欣祥  陈必河  黄凡  杨宗锋  王秉璋 《岩石学报》2008,24(3)

在印度-亚洲大陆碰撞过程中,俯冲板片断离触发了幔源岩浆底侵作用、下地壳部分熔融和冈底斯岩基带以及同岩基斑岩的产生.在此过程中,幔源岩浆分离结晶的产物、下地壳岩石部分熔融残余和地壳分异过程中下沉的镁铁质块体,构成了加厚下地壳.随着造山岩石圈的冷却和加厚下地壳重力不稳定性的增加,岩石圈拆沉作用触发了后碰撞斑岩型岩浆活动.与此相应,碰撞造山带斑岩型矿床可以形成于同碰撞和后碰撞两个不同的构造阶段.同碰撞成矿作用发生于岩基带形成时期,成矿物质主要来自于底侵幔源岩浆及更深部的含矿流体,其触发机制是俯冲板片的断离.后碰撞成矿作用发生于加厚下地壳冷却之后,成矿物质主要来自于新生矿源层和更深部的含矿流体,其触发机制为岩石圈拆沉作用.在同碰撞构造阶段,伴随着幔源岩浆的底侵作用,深部流体和幔源岩浆所含的成矿物质被注入到岩基岩浆中,与从岩基岩浆源区萃取的成矿物质汇聚在一起,一部分受岩基热的驱使上升成矿.由于流体中成矿元素的浓度强烈依赖于压力,另一部分成矿元素则滞留在难熔残余中形成新的矿源层.当发生岩石圈拆沉作用时,由此矿源层部分熔融形成的斑岩岩浆将相对富含成矿物质,导致碰撞造山带第二次成矿作用大爆发.  相似文献